catena-Poly[[bis(dimethylammonium) [cadmate(II)-bis(μ-1,1′:4′,1′′-terphenyl-3,3′′-dicarboxylato)]] dimethylformamide disolvate]
نویسندگان
چکیده
In the title compound, {(C(2)H(8)N)(2)[Cd(C(20)H(12)O(4))(2)]·2C(3)H(7)NO}(n), the Cd(II) ion lies on a twofold rotation axis and is in a distorted octa-hedral CdO(6) environment, defined by four O atoms of two μ(2)-coordinated 1,1':4',1''-terphenyl-3,3''-dicarboxyl-ate (DCT) ligands and two O atoms of two μ(1)-coordinated DCT ligands. Both types of DCT ligands act as bridging, forming a one-dimensional polymeric structure propagating parallel to [10].
منابع مشابه
Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2 O 2:O 6)bis[bis(1,10-phenanthroline-κ2 N,N′)cobalt(II)] dimethylformamide disolvate
The asymmetric unit of the title compound, [Co(2)(C(10)H(2)O(4)S(3))(2)(C(12)H(8)N(2))(4)]·2C(3)H(7)NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octa-hedral environment and is ligated to four N atoms of two 1,10-phenanthroline molecules and to two O atoms of two dithieno[3,2-b:2',3'-d]thio-phene-2,6-dicarb-oxy-l-ate...
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The title compound, [Ni(2)(C(12)H(12)N(2)O(4)S(3))(H(2)O)(4)]·2C(3)H(7)NO·3H(2)O, is made up of a centrosymmetric, bimetallic complex containing a 24-membered macrocyclic ring, two dimethyl-formamide and three water solvent mol-ecules. The Ni atom adopts a slightly distorted NiO(6) octahedral geometry arising from two O,O-bidentate ligands and two water molecules. There are inter-molecular O-H⋯...
متن کاملcatena-Poly[[[bis(N,N-dimethylformamide)iron(II)]-{μ-2,2′-bis(diphenylphosphinoyl)-N,N′-[(1R,2R)-cyclohexane-1,2-diyl]dibenzamide}] bis(perchlorate) N,N-dimethylformamide disolvate]
The title extended solid coordination compound, {[Fe(C(44)H(40)N(2)O(4)P(2))(C(3)H(7)NO)(2)](ClO(4))(2)·2C(3)H(7)NO}(n), was crystallized un-ex-pectedly from the reaction mixture containing the Trost ligand (1R,2R)-(+)-1,2-diamino-cyclo-hexane-N,N'-bis-(2'-di-phenyl-phosphinobenzo-yl) and Fe(ClO(4))(2)·6H(2)O in a 1:1 ratio in dimethyl-formamide (DMF) under reflux conditions. The polymeric comp...
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In the title coordination polymer, {[Cu(SO4)(C18H14N4O2)(H2O)]·C3H7NO} n , the Cu(II) ion is coordinated by two N atoms of two briding N,N'-bis-(pyridin-4-yl)isophthalamide ligands, two O atoms of two bridging SO4(2-) anions and a water mol-ecule, giving a distorted CuN2O3 square-pyramidal geometry. The whole repeating mol-ecular unit is generated by inversion symmetry. This leads to the format...
متن کاملBis{μ-1,3-bis[(benzimidazol-1-yl)methyl]benzene-κ2 N 3:N 3′}bis[dichloridozinc(II)] dimethylformamide disolvate
In the title compound, [Zn(2)Cl(4)(C(22)H(18)N(4))(2)]·2C(3)H(7)NO, the 1,3-bis-[(benzimidazol-1-yl)meth-yl]benzene ligand bridges two ZnCl(2) units, forming a centrosymmetric dinuclear mol-ecule. The Zn(II) atom shows a distorted tetra-hedral coordination within a Cl(2)N(2) donor set.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2010